GILSONITE:
Packing:
25 KG plastic bags or as per
customer request
Typical Uses /
Applications:
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GILSONITE
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Asphalt
Modifier
The use of modifiers to improve
the performance of bituminous road paving materials is
increasing worldwide. Gilsonite is used by asphalt producers,
road paving engineers and paving contractors who are concerned
with PG specifications, high performance and cost
effectiveness. Gilsonite, long known as a bitumen reinforcer
and hardening agent, also offers a unique combination of high
performance and economy for high stress paving applications.
The main benefit of Gilsonite is
in producing road pavement mixes of higher stability than
conventional ones. Gilsonite, a unique, natural hydrocarbon,
high in asphaltenes and nitrogen compounds, is a granular
solid that is fully compatible with bitumen. It can be melted
into hot bitumen, or it can be added during hot mix
manufacture. In either case, Gilsonite dissolves easily in
bitumen and achieves a uniform, easily workable hot mix.
The stability of Gilsonite-fortified
pavements makes them more resistant to deformation problems,
such as rutting and shoving, and increases the pavement's load
carrying ability. In addition, laboratory test and field
results show that increased deformation resistance can be
obtained while the pavement retains much of its original
ductility and ability to resist low temperature cracking.
Other positive benefits include increased resistance to water
stripping and aging.
Inks &
paints
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Gilsonite Resin is used as a
partial replacement for hydrocarbon resin, alkyd resin, rosin
modified hydrocarbon resin, phenolic modified rosin resins,
oxidized asphalt, and metal resinates.
In Heatset inks it is primarily
used as a replacement for hydrocarbon resin. It has its best
application in the carbon black grinding vehicles where it can
replace up to ½ of the hydrocarbon resin and up to ¼ of the
alkyd resin. It also can be used in the gelled let down
varnishes where it can replace up to ¼ of the rosin modified
hydrocarbon resin and up to ¼ of the phenolic modified rosin
resins. Unlike hydrocarbon resins, Gilsonite Resin has
functionality and will react with aluminum gelling agents.
In News ink formulas Gilsonite
Resin is used as a partial replacement for Gilsonite Resin or
oxidized asphalt. Gilsonite Resin has a solution viscosity
that is lower than GilsoniteResin ; so more resin can be added
to the formula at the same tack and viscosity. The increased
resin loading will give a News ink better rub-off properties.
In Gravure inks Gilsonite Resin
is used as a substitute for up to ½ of the metal Resinate in
the formula. Gilsonite Resin develops the carbon black more
efficiently than other wetting agents. Because of this higher
structure carbon blacks can be used while still maintaining
the gloss and adhesion characteristics that were attained
using low structure carbon black. The use of high structure
carbon black will yield ink with a bluer print tone, without
the addition of expensive alkali blue or iron blue toners.
Special grades of Gilsonite
called Selects are also standard ingredients in black ink
formulations and are used as additives in asphaltic paints and
varnishes.
Cement
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Gilsonite Resin is widely and
effectively used to prevent or cure loss of slurry circulation
while cementing oil and gas wells. The low specific gravity of
(1.05) and sealing characteristics of Gilsonite provides
qualities that make it effective against loss of the slurry to
permeable zones, natural and induced fractures, and caverns.
Since Gilsonite was first introduced to the industry in 1957,
more that 1 billion sacks of Gilsonite have been used in
cementing operations. As stated by Smith and Grant, the
properties of Gilsonite provide the following benefits in lost
circulation applications.
Provides low slurry density
without addition of large water volumes. Compressive strengths
are higher due to addition of solid particles rather than
water.
Compatible with other additives
since the solid hydrocarbon is chemically inert.
Protects against premature slurry
dehydration since Gilsonite is impermeable and nonporous.
Resists the effects of corrosive
waters as well as acidic and alkaline solutions.
Is strong enough to withstand
moderate squeeze pressures, but soft enough to permit pressure
deformation, thus providing an effective seal. This gives
Gilsonite Resin an advantage over ground coal, which does not
compress and does not have pressure deformation
characteristics.
Effective to bottomhole
temperatures of 350°F.
Resistant to dissolution by crude
oils.
Scours uncirculated drilling mud
and filter cake from borehole walls during slurry placement.
Six cases were cited in the paper
which illustrated the before and after effects of the use of
Gilsonite in cementing operations. Successful squeeze jobs,
prevention of cement fallback, and full or almost full fillup
during a cement operation were obtained. These cases cited
success in squeeze jobs after 15 unsuccessful attempts,
successful cementing in shallow wells with severe lost
circulation, reestablishment of lost circulation in wells used
for a waterflooding program, squeezing off corrosive damage in
oil casing, and successfully cementing in severely pressured
depleted wells.
There are three conclusions
regarding the use of Gilsonite in cementing operations:
Gilsonite slurries provide
effective and economical prevention and cure for loss of
cement circulation.
Gilsonite may be used in any type
of cementing system, with the optimum range being between 10
to 25 lb/sack.
Gilsonite slurries have been
reported to bridge in the casing when using bottom cementing
plugs. While situations may vary from well to well, this
should be considered by the user when high Gilsonite
concentrations are being planned.
Drilling Fluids
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For many years, Gilsonite has
been used in the oil field as an additive in drilling fluids.
Gilsonite, in various grades and formulations, has been used
to combat borehole instability problems, provide lubricity,
especially in highly deviated holes, and more recently as a
bridging agent to combat differential pressure sticking and
provide a low invasion coring fluid. It has been well
documented that appropriately formulated Gilsonite products
can minimize hole collapse in formations containing
water-sensitive, sloughing shales and reduce stuck pipe
problems by forming a thin wall cake and an inter-matrix
filter cake.
The causes of borehole
instability are numerous. The reasons for the instability can
be mechanical, chemical or physical in nature. Mechanical
problems include borehole erosion by high annular velocities,
adverse hydraulic stresses due to high annular pressures, hole
collapse from high swab and surge pressures due to excessive
wall cake, and stress erosion due to drill string movement.
Chemical alteration problems include hydration, dispersion,
and disintegration of shales due to the interaction of clays
with the mud filtrate. Physical instability problems include
the spalling and rock bursts of shales due to abnormal
pressure or overpressure relationships of hydrostatic and
formation pressures. Fracture and slippage along bedding
planes of hard, brittle shales and the collapse of fractured
shales above deviated holes are also physical problems
encountered while drilling troublesome shales. This problem
also occurs in non-deviated holes while drilling
over-pressured shales.
Borehole instability problems are
often referred to as sloughing, heaving, spalling, or
over-pressured shales, mud balls, mud rings, and many other
descriptive names. There are many solutions to these problems.
The use of additives to inhibit or partially inhibit the
swelling of shales has been well documented. Gilsonite
products play a key role in addressing these problems.
Gilsonite products are currently
being widely used in water based, oil based, and synthetic
based mud systems worldwide. Blended Gilsonite has proved to
be very effective in all water-based systems, with the
flagship product in this line being Bore-Plate(R) Shale
Stabilizer.
Bore-Plate Resin Shale Stabilizer
Bore-Plate Shale Stabilizer is a
proven, unique composition of Gilsonite grades and
dispersants, blended to provide optimum performance in water
based drilling fluids. Bore-Plate is effective in low and
high-temperature wells, stable in the presence of mud
contaminants, and tolerant to additions of diesel oil. It can
replace or complement sulphonated asphalts at a much lower
cost, while providing additional properties that sulphonated
asphalts lack.
Carbonaceous Foundry Sand Additive:
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Carbonaceous materials are
frequently added to sand molds used to make grey iron or pig
iron castings. The function of these additives is to reduce
the number of imperfections that occur in the casting process
and to release the casting from the sand mold more easily.
Currently, there are several
materials, including Gilsonite, that are used as a
carbonaceous additive in the foundry process. While there are
several theories as to the mechanics of how these additives
work, it is agreed that their major beneficial effects on the
sand mold are: (1) increased green strength; (2) increased dry
strength; (3) decreased hot strength; (4) decreased
permeability; and (5) increased mold hardness.
Foundry research and laboratory
testing demonstrates that Gilsonite, when used at lower levels
than other additives, equals or outperforms all other additive
materials. For example, studies conclude that Gilsonite is
critical to enhance the "casting peel" during shakeout.